Atomically Dispersed Heterobimetallic Catalysts for Cooperative C-H Bonds Activation

Introduction

The central objective of the DUO project is the development of original, well-defined, and highly dispersed heterobimetallic supported catalysts using a molecular approach. Its chemical foundation is to take advantage of both:

1. Metal-metal cooperative effects
2. Site-isolation benefits

in combination, to achieve unprecedented and highly reactive active sites. This will ultimately lead to new bond activation pathways to tackle challenging catalytic transformations.

Targeted Catalysts

Specifically, I target supported early/late pair-site catalysts, which are ideally suited to promote the heterolytic cleavage of strong C-H bonds.

Catalytic Applications

I will take advantage of this unusual reactivity in two classes of catalytic applications:

1. The late-stage isotopic labelling of organic substrates, such as active pharmaceutical ingredients.
2. CH4 and light alkanes valorization into higher hydrocarbons under non-oxidative conditions.

These catalytic targets are not only scientifically demanding from a fundamental perspective but also possess high potential industrial outcomes.

Approach and Innovation

A leap forward with respect to today’s state of the art is required to achieve these goals. I propose to use an interdisciplinary approach at the forefront of current knowledge, combining the benefits of innovative and tailored molecular chemistry with those of surface science and heterogeneous catalysis.

Conclusion

I have recently pioneered breakthrough concepts in this hot emerging research area, which are a strong guarantee for the success of the DUO project.